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- W2130962848 abstract "Several substituted salicylanilines (I) are studied by 1H (chemical shifts) and 13C (chemical shifts and T1 relaxation times) NMR in order to obtain information on molecular geometry changes and the transmission of the electronic effects due to substituents, as well as on the relative rates of the overall molecular tumbling and of the flipping of the phenyl rings. In particular, a good linear correlation of the OH proton shifts (affected by intramolecular hydrogen bonding) with Hammett's σ constants for p-substitution in the aniline moiety is found. Changes in rigidity of the rings expected as a result of the OH...N interaction and of p-substitution are reflected on the phenyl carbon relaxation times." @default.
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- W2130962848 date "1988-01-01" @default.
- W2130962848 modified "2023-09-27" @default.
- W2130962848 title "1H and 13C nmr studies of salicylalanilines" @default.
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- W2130962848 doi "https://doi.org/10.1016/s0040-4020(01)85103-6" @default.
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