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- W2130993910 abstract "Anionic metal oxide clusters, so-called polyoxometalates, can be developed as molecular model compounds to mimic the chemical and photochemical reactivity of solid-state metal oxides on the molecular level. Inspired by the well-known visible-light photocatalyst BiVO4, the first molecular bismuth vanadium oxide has been synthesized to investigate the chemical and photochemical similarities between the solid-state and molecular compounds. The cluster H3[(Bi(dmso)3)4V13O40]⋅ca. 4 DMSO was obtained from simple precursors in almost quantitative yield. Structural analysis showed that the cluster shell is based on the unusual all-vanadium ε-Keggin framework [ε-V12O40]15−, which is stabilized by coordination of four BiIII centers. The acidic character of the three cluster protons was demonstrated by titration studies. The cluster shows promising photocatalytic properties in visible-light photooxidation reactions and has high activity (turnover number >1200), high quantum yield (Φ=7.6 %), and good recyclability, which make it a promising first example of a new class of heterometallic polyoxometalates." @default.
- W2130993910 created "2016-06-24" @default.
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- W2130993910 date "2012-07-24" @default.
- W2130993910 modified "2023-10-16" @default.
- W2130993910 title "Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide" @default.
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- W2130993910 doi "https://doi.org/10.1002/chem.201200404" @default.
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