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- W2131133710 abstract "The thermodynamic parameters for the homogeneous phase reaction NO–3= NO–2+½O2(a) in the (Na,K)NO3 eutectic melt has been determined in the temperature range 500–700 K; ΔHa= 114 kJ mol–1 and ΔS0a= 62 J mol–1 K–1. Appropriate catalysts have been used to favour the establishment of equilibrium conditions. The results are compared critically with all available data for reaction (a) in various nitrate solvents. On the basis of the van't Hoff equation and data we obtained previously for the “anhydrous” disproportionation of superoxide, the thermodynamic parameters for the reaction NO–3+½O2–2= NO–2+ O–2(b) have been calculated; ΔHb= 95 kJ mol–1 and ΔS0b= 84 J mol–1 K–1." @default.
- W2131133710 created "2016-06-24" @default.
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- W2131133710 date "1976-01-01" @default.
- W2131133710 modified "2023-09-26" @default.
- W2131133710 title "Thermodynamics of the systems NO–3= NO–2+½O2 and NO–3+½O2–2= NO–2+ O–2 in molten alkali nitrates" @default.
- W2131133710 doi "https://doi.org/10.1039/f19767201512" @default.
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