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- W2131232282 abstract "Abstract The reactions of cis ‐PtCl 2 (PR 3 ) 2 (R = OPh, OMe) with 1 equiv. of lithium phosphoranide generated from a bis(naphth‐1,8‐diyl‐8‐oxy)phosphorane lead to the formation of cis ‐monophosphoranido complexes with high stereospecificity. The reaction of cis ‐PtCl 2 (PMe 3 ) 2 with 1 equiv. of the lithium phosphoranide afforded a trans ‐monophosphoranido complex, exclusively. Hitherto unknown trans ‐bis(phosphoranido)platinum(II) complexes were obtained as major products in the reactions of cis ‐PtCl 2 (PR 3 ) 2 (R = OPh, OMe, Me) with an excess of the lithium phosphoranide. The stereochemistry was confirmed by X‐ray structural analysis of the bis(phosphoranido) complex bearing triphenyl phosphites. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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- W2131232282 date "2009-12-01" @default.
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- W2131232282 title "Syntheses and Characterization of Novel <i>trans</i> ‐Bis(phosphoranido)platinum(II) Complexes: Reactions of Lithium Bis(naphth‐1,8‐diyl‐8‐oxy)phosphoranide with <i>cis</i> ‐PtCl <sub>2</sub> (PR <sub>3</sub> ) <sub>2</sub> (R = OPh, OMe, Me)" @default.
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- W2131232282 doi "https://doi.org/10.1002/ejic.200900834" @default.
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