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- W2131323489 abstract "Using X-ray diffraction techniques, thermal expansion and compressibility were measured on the orthorhombic compounds HfTiO4, Hf1.26Ti0.74O4, and ZrTiO4 (both quenched and cooled slowly from 1300°C). The thermal expansion of HfTiO4 is highly anisotropic; the thermal expansion coefficients along the crystallographic axes are αa=+(8.7±0.5)×10−6°C−1, αb=−(5.2±0.5)×10−6°C−1, and αc=+ (5.3±0.5)×10−6°C−1. The thermal expansion of Hf1.26Ti0.74O4 was similar to that of HfTiO4 but that of ZrTiO4 was markedly less anisotropic. The compressibilities of HfTiO4 and ZrTiO4 also differed markedly. All compounds investigated, however, behaved similarly in exhibiting a polymorphic transition to a high-pressure phase having the monoclinic baddeleyite (ZrO2) structure. The polymorphism can be explained qualitatively on the basis of crystal structure." @default.
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- W2131323489 date "1972-08-01" @default.
- W2131323489 modified "2023-10-15" @default.
- W2131323489 title "Thermal Expansion, Compressibility, and Polymorphism in Hafnium and Zirconium Titanates" @default.
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- W2131323489 doi "https://doi.org/10.1111/j.1151-2916.1972.tb11323.x" @default.
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