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- W2131346038 abstract "Any physical process which results in a particle being labelled i.e. ionised or excited, can in principle be used as the basis for a method of chemical analysis. In the case of ion-surface interaction there are several different types of labelled particles, depending on the particular interaction event involved in the excitation or ionisation. In this paper we consider those particles either scattered or sputtered, which survive the ion-surface interaction in an excited state and decay radiatively away from the surface. We examine the state of our understanding of the excitation processes leading to an ion or atom which can emit radiatively, and conclude that our understanding is not sufficiently good to allow us to develop an analysis technique from the theory of the process. We then describe some experiments which involve attempts at quantitative analysis by comparing photon yields from Nb/V alloys with photon yields from pure targets. In a UHV environment, a rough analysis is possible but in an oxygen-contaminated situation, the photon yield enhancement is shown to depend on the composition of the alloy so that quantitative analysis is not possible. We conclude that spectroscopic techniques based on photon emission from sputtered atoms do not provide a universally applicable method of analysis, though in specific cases they may be applicable." @default.
- W2131346038 created "2016-06-24" @default.
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- W2131346038 date "1982-08-01" @default.
- W2131346038 modified "2023-09-27" @default.
- W2131346038 title "Outer shell excitation during ion bombardment and its application to surface analysis" @default.
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- W2131346038 doi "https://doi.org/10.1016/0378-5963(82)90017-4" @default.
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