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• W2131356710 abstract "As part of a study in which electromotive force (emf) measurements are used to determine thermodynamic properties of sucrose solutions approximating fruit juice, it was necessary to determine the standard potential of the silver-silver chloride electrode in this medium. Emf measurements of cells of the type: Pt; H2 (g, 1 atm) | HCl (m) in 10 wt% sucrose/H2O | AgCl; Ag, where molality = 0·005 to 0·05 over the temperature range 0 to 25°C, allowed the calculation of the molal standard potential, E0m, of the Ag-AgCl electrode in the dilute sucrose mixture. Values obtained were fitted to an equation second-order in temperature, E0m = 0·23162 − 4·9204 × 10−4t − 3·0500 × 10−6t2 (t = temperature (°C), sd = 0·02 mV). The mean activity coefficient of HCl, γ±, in the sucrose-water mixture can be described within the experimental precision of the data to 0·10 m at 25°C using a simple Debye-Hückel model which incorporates an ion-size parameter of 7·8 Å. The results provide a basis for precision emf measurements in dilute sucrose-water mixtures." @default.
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• W2131356710 creator A5001151712 @default.
• W2131356710 date "1990-01-01" @default.
• W2131356710 modified "2023-10-03" @default.
• W2131356710 title "Standard potential of the silver-silver chloride electrode and mean activity coefficient of hydrochloric acid in 10 wt% sucrose/water from 0 to 25°C" @default.
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• W2131356710 doi "https://doi.org/10.1016/0308-8146(90)90039-7" @default.
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