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- W2131542211 abstract "Cobalt mediated tandem radical cyclisations, viz (1), → (3), )5) → (7), (10) → (13), can be carried out in sequence with isolation of intermediate organocobalt reagents, i.e (2), (6), (11), or alternatively in a ‘one-pot’ operation. In the presence of reactive radical trapping agents (e.g.3O2, TEMPO) the intermediate organocobalt reagents undergo functional group exchange, [e.g. (11) → (15) and (14) respectively], whereas in the presence of less reactive styrene, a cascade of cobalt group transfer-radical trapping-tandem radical cyclisation - dehydrocobaltation reactions result allowing, for example, the five step ‘one-pot’ synthesis of (12) from (10) in 20% overall yield." @default.
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- W2131542211 date "1992-05-01" @default.
- W2131542211 modified "2023-09-25" @default.
- W2131542211 title "Cascade cobalt group transfer - radical trapping - tandem radical cyclisation reactions in synthesis" @default.
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- W2131542211 doi "https://doi.org/10.1016/s0040-4039(00)78877-0" @default.
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