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- W2131567495 abstract "Lithium carbenoids are versatile compounds for synthesis owing to their intriguing ambiphilic behavior. Although this class of compounds has been known for several years, few solid-state structures exist because of their high reactivity and often low thermal stability. Using cryo X-ray techniques, we were now able to elucidate the first solid-state structure of a Li/F alkyl carbenoid, pentafluoroethyllithium (LiC2F5), finally yielding a prototype for investigating structure-reactivity relationships for this class of molecules. The compound forms a diethyl ether-solvated dimer bridged by a rare C-F-Li link. Complementary NMR spectroscopy studies in solution show dynamic processes and indicate rapid exchange of starting material and product. Theoretical investigations help to understand the formation of the observed unusual structural motif." @default.
- W2131567495 created "2016-06-24" @default.
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- W2131567495 date "2014-09-09" @default.
- W2131567495 modified "2023-09-29" @default.
- W2131567495 title "Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium" @default.
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- W2131567495 doi "https://doi.org/10.1002/anie.201406564" @default.
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