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- W2131567605 abstract "Abstract Palladium-catalysed intramolecular asymmetric Heck reactions were performed on triflate 5 using complexes derived from BINAP and a range of oxazoline-containing phosphinamine ligands. The optimum ee obtained was 85% employing the t-butyl-substituted ferrocenyloxazoline ligand 6 . The isomer distribution of the product spirooxindoles was dependent on the ligand chosen, with the oxazoline-containing ligands showing an increased selectivity (up to 99:1) for the Δ2,3-isomer 3 compared to BINAP (optimum 75:25)." @default.
- W2131567605 created "2016-06-24" @default.
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- W2131567605 date "2002-12-01" @default.
- W2131567605 modified "2023-10-03" @default.
- W2131567605 title "A comparative study of diphosphine and phosphinamine palladium complexes on a new substrate for the intramolecular asymmetric Heck reaction" @default.
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- W2131567605 doi "https://doi.org/10.1016/s0040-4039(02)02429-2" @default.
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