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- W2131710099 abstract "The reaction of bromine with a variety of dimethyl acetals at − 60° in sulfur dioxide is described. Electrophilic attack of bromine on oxygen leads to methyl hypobromite (CH3OBr) together with mono methoxycarbenium bromide or - depending on the stability of the cation - its covalent counterpart, the α-bromo-ether. The reaction is catalysed by acids. Acetals derived from linear and cyclic carbonyl compounds react in this way with one exception: with 1,1-dimethoxycyclopropane, the acetal of cyclopropanone, electrophilic attack by bromine is not on oxygen, but on the cyclopropane ring. Ring rupture leads to a relatively stable di methoxycarbenium ion." @default.
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- W2131710099 date "2010-09-02" @default.
- W2131710099 modified "2023-10-17" @default.
- W2131710099 title "The reaction of acetals with bromine in sulfur dioxide" @default.
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- W2131710099 doi "https://doi.org/10.1002/recl.19700890510" @default.
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