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• W2131739365 abstract "The copolymerizations of a gaseous monomer (ethylene) and a liquid monomer (vinyl acetate) via emulsion and miniemulsion polymerizations are reported. Reactions in which the vinyl acetate was introduced in both batch and semibatch modes are carried out. (Ethylene introduction is always in a semibatch model since the polymerization is carried out under a constant pressure of ethylene in the reactor headspace.) The results are compared, drawing the conclusion that miniemulsion copolymerization has an advantage over conventional emulsion polymerization for monomers with very low water solubility (including gaseous monomers) due to their nucleation in monomer droplets without transport through the aqueous phase." @default.
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• W2131739365 date "2009-08-04" @default.
• W2131739365 modified "2023-10-02" @default.
• W2131739365 title "Miniemulsion Copolymerization of Ethylene and Vinyl Acetate" @default.
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• W2131739365 doi "https://doi.org/10.1002/mren.200900023" @default.
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