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• W2131828776 abstract "Abstract A series of new M[(dcbdt) 2 ] − z complexes of the dicyanobenzodithiolate (dcbdt) ligand with a range of transition metals (M = Co, Pd, Pt, Cu, Au and Zn) in different oxidation states ( z = 0.4, 1, 2) were prepared as their n Bu 4 N salts and characterised by X‐ray diffraction, cyclic voltammetry, EPR and static magnetic susceptibility. Their properties are discussed in comparison with the Ni and Fe analogues described by us recently. The structures of these complexes belong to four distinct groups: i) the Zn II compound 10 is triclinic P $bar 1$ with the metal in a tetrahedral coordination geometry; ii) other M II complexes [M = Pt ( 8 ), Pd ( 7 ), Co ( 3 ) and Cu ( 5 )] are monoclinic C 2/ m , and are isostructural with the Ni II analogue, presenting a perfectly planar square geometry; iii) the Co III compound 4 is triclinic P $bar 1$ , and isostructural with the Fe and Ni analogues, with a strong dimerisation of the M(dcbdt) 2 units and the metal in a square‐pyramidal coordination geometry; iv) the M III salts with M = Au ( 2 ), Cu ( 6 ) and Pt ( 9 ) are monoclinic P 2 1 / c and the complexes are arranged as pseudo‐dimers. The EPR and static magnetic‐susceptibility measurements show that the Co II ( 3 ), Cu II ( 5 ), Pt III ( 9 ) and Co III ( 4 ) complexes are paramagnetic corresponding to an S = 1/2 state, except for Co III , which is in a high‐spin S = 1 configuration. The solid state EPR spectra of the Co II compound presents a hyperfine structure typical of the I = 7/2 59 Co. The temperature dependence of the paramagnetic susceptibility of the Pt III compound follows a singlet‐triplet model with a dimer antiferromagnetic coupling, J , of 984 K. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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• W2131828776 date "2004-03-01" @default.
• W2131828776 modified "2023-10-15" @default.
• W2131828776 title "A Series of Transition Metal Bis(dicyanobenzenedithiolate) Complexes [M(dcbdt)₂] (M = Fe, Co, Ni, Pd, Pt, Cu, Au and Zn)" @default.
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• W2131828776 doi "https://doi.org/10.1002/ejic.200300476" @default.
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