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- W2131964585 abstract "To investigate the effects of the dendrimer backbone on catalysis, a series of monomeric and dendritic SCS-pincer Pd-complexes was synthesized and tested in two different Pd(II)-catalyzed reactions. To this end, the three novel polar PAMAM dendrimer-immobilized SCS-pincer Pd-complexes 3, 4, and 5, and the two apolar carbosilane dendrimer-immobilized complexes 7 and 8 were compared to three monomeric analogues 1, 2 and 6. These complexes were investigated in the cross-coupling reaction between vinyl epoxide and styrylboronic acid and the auto-tandem reaction of cinnamyl chloride, hexamethylditin, and 4-nitrobenzaldehyde. The differences in catalytic rate and product selectivity for these complexes are described and discussed. For the cross coupling reaction, the PAMAM dendrimer-immobilized complexes were found to give a similar reaction rate, but a higher product selectivity than their monomeric counterparts. The carbosilane complexes showed a lower reaction rate and similar product selectivity. These observations are explained in view of dendrimer aggregation and peripheral group backfolding." @default.
- W2131964585 created "2016-06-24" @default.
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- W2131964585 date "2011-01-01" @default.
- W2131964585 modified "2023-10-16" @default.
- W2131964585 title "The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes" @default.
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- W2131964585 doi "https://doi.org/10.1039/c1nj20366e" @default.
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