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• W2132030714 endingPage "11082" @default.
• W2132030714 startingPage "11078" @default.
• W2132030714 abstract "An acid–base reaction to speed up a sluggish catalytic cycle! AcOH as the solvent enables extraordinarily fast and efficient PdII-catalysed, direct intramolecular allylic aminations, assisting the benzoquinone-mediated palladium reoxidation and ionisation of the intermediate palladium complexes (see scheme). The structural and energetic aspects of such a key step of the catalytic cycle are illustrated by means of a detailed DFT analysis." @default.
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• W2132030714 date "2009-10-20" @default.
• W2132030714 modified "2023-10-18" @default.
• W2132030714 title "Striking AcOH Acceleration in Direct Intramolecular Allylic Amination Reactions" @default.
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• W2132030714 doi "https://doi.org/10.1002/chem.200901946" @default.
• W2132030714 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19795438" @default.
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