Matches in SemOpenAlex for { <https://semopenalex.org/work/W2132058409> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2132058409 endingPage "1992" @default.
- W2132058409 startingPage "1987" @default.
- W2132058409 abstract "The organometallic dimers [{Co2(CO)6}2(diyne)] [diyne = C6H4(CO2CH2C2H)2-1,2 1, HC2CH2OC6H4OCH2C2H 2 or HC2(CH2)5C2H 3] have been synthesized from reactions between [Co2(CO)8] and the appropriate diyne ligands. However, the reaction of [Co2(CO)8] with diprop-2-ynyl ether HC2CH2OCH2C2H under similar conditions gave the expected product [{Co2(CO)6}2(µ-HC2CH2OCH2C2H)] 4 and the unexpected product [Co4(CO)10(µ-CO){µ4-η∶η3-CC(CH2OCH2)CCH2}] 5. The products have been characterised by infrared, 1H NMR spectroscopy and C/H analyses, and 2, 4 and 5 also by single-crystal X-ray crystallography. In 2 and 4 both “yne” fragments of the diyne ligand are bonded to a Co2(CO)6 fragment with the CC vector essentially perpendicular to the Co–Co vector. However, in 5 hydrogen migration and new C–C bond formation has led to novel structural features, such as µ3-CCo3 and η3-C3Co units and a “C4O” ring." @default.
- W2132058409 created "2016-06-24" @default.
- W2132058409 creator A5010644954 @default.
- W2132058409 creator A5020495043 @default.
- W2132058409 creator A5028035604 @default.
- W2132058409 creator A5056787291 @default.
- W2132058409 creator A5073501391 @default.
- W2132058409 creator A5082485801 @default.
- W2132058409 date "1999-01-01" @default.
- W2132058409 modified "2023-09-23" @default.
- W2132058409 title "Synthesis and characterisation of some dimeric η2-diyne compounds of cobalt" @default.
- W2132058409 cites W1967505560 @default.
- W2132058409 cites W1968145455 @default.
- W2132058409 cites W1968915907 @default.
- W2132058409 cites W2000246695 @default.
- W2132058409 cites W2000717046 @default.
- W2132058409 cites W2006081298 @default.
- W2132058409 cites W2019702507 @default.
- W2132058409 cites W2069115374 @default.
- W2132058409 cites W2314726533 @default.
- W2132058409 cites W2319990681 @default.
- W2132058409 cites W2332091730 @default.
- W2132058409 cites W2335343335 @default.
- W2132058409 cites W3137271136 @default.
- W2132058409 doi "https://doi.org/10.1039/a900706g" @default.
- W2132058409 hasPublicationYear "1999" @default.
- W2132058409 type Work @default.
- W2132058409 sameAs 2132058409 @default.
- W2132058409 citedByCount "12" @default.
- W2132058409 countsByYear W21320584092012 @default.
- W2132058409 crossrefType "journal-article" @default.
- W2132058409 hasAuthorship W2132058409A5010644954 @default.
- W2132058409 hasAuthorship W2132058409A5020495043 @default.
- W2132058409 hasAuthorship W2132058409A5028035604 @default.
- W2132058409 hasAuthorship W2132058409A5056787291 @default.
- W2132058409 hasAuthorship W2132058409A5073501391 @default.
- W2132058409 hasAuthorship W2132058409A5082485801 @default.
- W2132058409 hasConcept C115624301 @default.
- W2132058409 hasConcept C116569031 @default.
- W2132058409 hasConcept C153642686 @default.
- W2132058409 hasConcept C155647269 @default.
- W2132058409 hasConcept C170493617 @default.
- W2132058409 hasConcept C178790620 @default.
- W2132058409 hasConcept C185592680 @default.
- W2132058409 hasConcept C2780378348 @default.
- W2132058409 hasConcept C2780407432 @default.
- W2132058409 hasConcept C32909587 @default.
- W2132058409 hasConcept C515602321 @default.
- W2132058409 hasConcept C55493867 @default.
- W2132058409 hasConcept C71240020 @default.
- W2132058409 hasConcept C8010536 @default.
- W2132058409 hasConcept C91967747 @default.
- W2132058409 hasConceptScore W2132058409C115624301 @default.
- W2132058409 hasConceptScore W2132058409C116569031 @default.
- W2132058409 hasConceptScore W2132058409C153642686 @default.
- W2132058409 hasConceptScore W2132058409C155647269 @default.
- W2132058409 hasConceptScore W2132058409C170493617 @default.
- W2132058409 hasConceptScore W2132058409C178790620 @default.
- W2132058409 hasConceptScore W2132058409C185592680 @default.
- W2132058409 hasConceptScore W2132058409C2780378348 @default.
- W2132058409 hasConceptScore W2132058409C2780407432 @default.
- W2132058409 hasConceptScore W2132058409C32909587 @default.
- W2132058409 hasConceptScore W2132058409C515602321 @default.
- W2132058409 hasConceptScore W2132058409C55493867 @default.
- W2132058409 hasConceptScore W2132058409C71240020 @default.
- W2132058409 hasConceptScore W2132058409C8010536 @default.
- W2132058409 hasConceptScore W2132058409C91967747 @default.
- W2132058409 hasIssue "12" @default.
- W2132058409 hasLocation W21320584091 @default.
- W2132058409 hasOpenAccess W2132058409 @default.
- W2132058409 hasPrimaryLocation W21320584091 @default.
- W2132058409 hasRelatedWork W1972899349 @default.
- W2132058409 hasRelatedWork W1974286671 @default.
- W2132058409 hasRelatedWork W1975351927 @default.
- W2132058409 hasRelatedWork W1979749954 @default.
- W2132058409 hasRelatedWork W2013979702 @default.
- W2132058409 hasRelatedWork W2042372453 @default.
- W2132058409 hasRelatedWork W2088690592 @default.
- W2132058409 hasRelatedWork W2120934592 @default.
- W2132058409 hasRelatedWork W2145006407 @default.
- W2132058409 hasRelatedWork W2371166865 @default.
- W2132058409 isParatext "false" @default.
- W2132058409 isRetracted "false" @default.
- W2132058409 magId "2132058409" @default.
- W2132058409 workType "article" @default.