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• W2132087474 abstract "The pronounced glass-forming tendencies of alloys of S and Se with Ge and/or As are discussed topologically. An atomic model is introduced which for predominantly covalent forces constitutes the first microscopic realization of Kauzmann's description of the glass transition as an entropy (not enthalpy or volume) crisis. The model contains no adjustable parameters and predicts the glass-forming tendency as a function of composition in excellent agreement with experiment. Several related properties, including phase diagrams, radial distribution functions and crystal structures are discussed in the context of chemical bonding and short-range order in the non-crystalline covalent networks of these materials." @default.
• W2132087474 created "2016-06-24" @default.
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• W2132087474 date "1979-10-01" @default.
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• W2132087474 title "Topology of covalent non-crystalline solids I: Short-range order in chalcogenide alloys" @default.
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• W2132087474 doi "https://doi.org/10.1016/0022-3093(79)90033-4" @default.
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