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- W2132202279 abstract "Abstract An asymmetric reaction of chiral imines with silyl ketene acetals, prepared from (3R)-hydroxybutyrate, mediated by a boron reagent is described. The method successfully affords β-amino esters with high diastereoselectivity, which can be converted to optically pure β-lactams. This result indicated that a formal total synthesis of (+)-thienamycin is achieved by a simple and practical procedure." @default.
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- W2132202279 date "1993-11-01" @default.
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- W2132202279 title "Novel asymmetric synthesis of β-lactams with 3-(1′-hydroxyethyl) substituents: boron reagent mediated aldol reaction of chiral imines and silyl ketene acetals derived from 3-hydroxybutyrate" @default.
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- W2132202279 doi "https://doi.org/10.1016/s0960-894x(01)80951-3" @default.
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