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- W2132243951 abstract "Athermal chains of various stiffness embedded in several types of lattices were analyzed with respect to their pair distribution function G(R). Extrapolation to infinite chain-length on a reduced distance scale made all the G(R) data coincide within extremely narrow limits, thus suggesting the existence of a universal pair distribution function for polymers in good solvents in the long-chain limit. The ratio –ln(G(R))/Z(R) with Z(R) being the reduced distribution of overlaps is also universal in type and varies only little with distance R. Further, a likewise universal function could be established that allows the construction of Z(R) from the Flory–Krigbaum expression taking into account not only the deviations from Gaussian behavior but also the effect of intramolecular repulsion present in athermal chains." @default.
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- W2132243951 date "2012-09-28" @default.
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- W2132243951 title "Toward a Universal Behavior of Linear Athermal Model Chains in the Limit of Infinite Chain-length" @default.
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- W2132243951 doi "https://doi.org/10.1002/mats.201200040" @default.
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