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- W2132249852 abstract "The reaction between the sodium salt of 2-oxyphosphinine and diphenylchlorophosphine leads to 2-diphenylphosphinite phosphinine as a new chelating ligand. Copper(I) complexes are easily and quantitatively obtained when this compound is reacted with CuIX (X = Cl, Br, I). The optical properties of these complexes were investigated; all of them show phosphorescence in the solid state at room temperature and emit orange-red light in the range 658 to 702 nm with average lifetimes from 19.98 to 25.01 μs. The emission wavelength is tuned by the nature of the halide ligand: Cl–, which leads to a larger ligand-field splitting, gives the longest emission wavelength, whereas I–, which generates a smaller ligand-field splitting, leads to the shortest emission wavelength." @default.
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- W2132249852 date "2015-11-09" @default.
- W2132249852 modified "2023-09-26" @default.
- W2132249852 title "Synthesis and Photoluminescence Properties of Cu <sup>I</sup> Complexes with Chelating Phosphinito Phosphinine Ligands" @default.
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- W2132249852 doi "https://doi.org/10.1002/ejic.201500933" @default.
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