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- W2132335564 abstract "Tris(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)diplatinum[11057-89-9] C24H54O3Pt2Si6 (MW 949.36)InChI = 1S/3C8H18OSi2.2Pt/c3*1-7-10(3,4)9-11(5,6)8-2;;/h3*7-8H,1-2H2,3-6H3;;InChIKey = YPKDGQOQZAYDOB-UHFFFAOYSA-NBis(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)platinum[81032-58-8] C16H36O2PtSi4 (MW 567.88)InChI = 1S/2C8H18OSi2.Pt/c2*1-7-10(3,4)9-11(5,6)8-2;/h2*7-8H,1-2H2,3-6H3;InChIKey = JTSZXOTUXGOAJS-UHFFFAOYSA-N(reagent may be used hydrosilylation of alkenes and alkynes, as well as for the reduction of amides)Alternate Names: Karstedt's catalyst.1Physical Data: 1H NMR (C6D6) δ −0.25, −0.13, 0.15, 0.30, 0.51, 0.52 (each s, 6H, SiMe), 2.84–3.88 (18 overlapping multiplets).Solubility: sol in ether, hexane, toluene, xylene, and vinyl-terminated poly(dimethylsiloxane).Form Supplied in: colorless oil; commercially available as platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution in vinyl-terminated poly(dimethylsiloxane) [68478-92-2].Preparative Methods: prepared from H2PtCl61, 2 or Pt(cod)2 and 1,1,3,3-tetramethyl-1,3-divinyldisiloxane.3 Alternatively, it is accessible from PtCl2(cod) using SmI2 as reducing reagent.4 X-ray crystallography has been used to confirm the solid-state structure of tris(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)diplatinum.3 In solution, Karstedt's catalyst is a dynamic mixture of tris(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)diplatinum and bis(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)platinum;5, 6 a single species is obtained when in solution in vinyl-terminated poly(dimethylsiloxane).7Handling, Storage, and Precautions: must be stored in solution in vinyl-terminated poly(dimethylsiloxane) to ensure long-term stability." @default.
- W2132335564 created "2016-06-24" @default.
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- W2132335564 date "2011-03-15" @default.
- W2132335564 modified "2023-09-30" @default.
- W2132335564 title "Tris(1,1,3,3-tetramethyl-1,3-divinyldisiloxane)diplatinum" @default.
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- W2132335564 doi "https://doi.org/10.1002/047084289x.rn01301" @default.
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