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- W2132380437 abstract "This paper reports the Raman spectra of the complexes SF4,SbF5,SeF4,SbF5, TeF4,SbF5, and SeF4,AsF5 in the molten state, the Raman spectra of the salts KSbF6 in NN-dimethylformamide and KAsF6 in acetonitrile, the infrared spectra of KSbF6 and KAsF6 as Nujol mulls in the range 650–2000 cm.–1, and the Raman spectrum of liquid arsenic trifluoride. Interpretation of the spectra of KSbF6 and KAsF6 leads to assignments for the anions SbF6– and AsF6–. The spectra of the molten complexes SF4,SbF5, SeF4,SbF5, and SeF4,AsF5 can be interpreted in terms of the ionic formulations SF3+SbF6–, SeF3+SbF6–, and SeF3+AsF6–. Assignments are made for the SF3+ and SeF3+ ions, and are compared with those for the isoelectronic PF3 and AsF3 molecules. In the case of the complex TeF4,SbF5 the situation is less clear and no decision is possible between the two more plausible alternatives of ionisation into distorted ions TeF3+ and SbF6– or a fluorine bridged structure F3TeFSbF5. Finally, the stability and degree of ionisation in complexes of this type are discussed in terms of the relative stabilities of the anions and cations that would be formed. Investigations were also made of the systems SF4/AsF3, SeF4/AsF3, and TeF4/AsF3. No evidence for complex formation was obtained." @default.
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- W2132380437 date "1968-01-01" @default.
- W2132380437 modified "2023-09-30" @default.
- W2132380437 title "The vibrational Raman spectra of some complexes formed between the tetrafluorides of Group VI elements and antimony and arsenic pentafluorides" @default.
- W2132380437 doi "https://doi.org/10.1039/j19680001688" @default.
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