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- W2132399191 endingPage "12826" @default.
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- W2132399191 abstract "Abstract A catalytic enantioselective nucleophilic aromatic substitution reaction which yields axially chiral biaryl derivatives in excellent yields with e.r. values of up to 97:3 has been developed. This process uses a chiral counterion to direct the addition of thiophenolate to a prochiral dichloropyrimidine by a tandem desymmetrization/kinetic resolution mechanism. The products can be derivatized to a range of atropisomeric structures without any reduction in enantioenrichment, thus offering access to unexplored chiral biaryl architectures." @default.
- W2132399191 created "2016-06-24" @default.
- W2132399191 creator A5034938361 @default.
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- W2132399191 date "2014-09-24" @default.
- W2132399191 modified "2023-10-18" @default.
- W2132399191 title "Catalytic Enantioselective Synthesis of Atropisomeric Biaryls: A Cation-Directed Nucleophilic Aromatic Substitution Reaction" @default.
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- W2132399191 doi "https://doi.org/10.1002/anie.201408205" @default.
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