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- W2132666612 abstract "The crystallization of Al2O3-rich glasses in the system SiO2-Al2O3 which were prepared by flame-spraying and/or splat-cooling was studied by DTA, electron microscopy, and X-ray diffraction. Over a wide range of compositions, the crystallization temperature (Tx) remained near 1000°C, changing smoothly with composition. In all cases crystallization of mullite was detected by X-ray diffraction. In the low-Al2O3 region, coarsening of the microstructure during crystallization was observed by electron microscopy. In the high-Al2O3 region mullite and γ-Al2O3 cocrystallized; this behavior may be interpreted as evidence of a cooperative process of crystallization at the respective Tx's. The crystallite size of the mullite immediately after rapid crystallization increased continuously with increasing Al2O3 content. In light of the Tx data, the adequacy of the evidence for the proposed metastable miscibility gap in the SiO2-Al2O3 system is questioned." @default.
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- W2132666612 date "1973-12-01" @default.
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- W2132666612 title "Rapid Crystallization of SiO2-Al2O3 Glasses" @default.
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- W2132666612 doi "https://doi.org/10.1111/j.1151-2916.1973.tb12442.x" @default.
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