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- W2132706693 abstract "In view of biological activities of both 1,3-dioxolanyl nucleosides and C-nucleosides, d- and l-1,3-dioxolanyl C-nucleosides have been synthesized as potential antiviral and/or anticancer agents. Asymmetric synthesis of four new optically pure d- and l-1,3-dioxolanyl triazole C-nucleosides has been accomplished via key intermediate 5a and 5b starting from d- and l-2,3-O-isopropylidene glyceraldehyde. The stereochemical assignments of synthesized compounds were unambiguously made based on NMR studies as well as X-ray crystallographic studies. The synthesized nucleosides have been evaluated against HIV and hepatitis B virus, however, no significant antiviral activity was observed." @default.
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- W2132706693 date "1999-07-01" @default.
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- W2132706693 title "Asymmetric synthesis of (2′R,4′R) and (2′S,4′S)-1,3-dioxolanyl triazole C-nucleosides" @default.
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- W2132706693 doi "https://doi.org/10.1016/s0040-4020(99)00499-8" @default.
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