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• W2132777932 abstract "A series of new tetramethylcyclopentadienyl-functionalised N-heterocyclic carbene ligands with different wingtip substituents have been prepared and characterised. These ligands have been successfully coordinated to nickel affording complexes of the general type (Cp*-NHCR)NiX (X = Cl, I). These well-defined nickel complexes selectively catalysed the coupling of aromatic thiols with Et3SiH to give the corresponding silylthioethers (RSSiEt3). The nickel complexes bearing ethyl, iso-butyl, and n-butyl wingtips displayed comparable catalytic efficiency, while the nickel complex bearing a methyl substituent on the wingtip was the worst performing catalyst." @default.
• W2132777932 created "2016-06-24" @default.
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• W2132777932 date "2014-01-01" @default.
• W2132777932 modified "2023-10-18" @default.
• W2132777932 title "Dehydrogenative coupling of aromatic thiols with Et₃SiH catalysed by N-heterocyclic carbene nickel complexes" @default.
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• W2132777932 doi "https://doi.org/10.1039/c3dt52052h" @default.
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