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• W2132877164 abstract "The domino-Heck double cyclisation of the arylbromides 1, which contain an allylsilane and an alkyne moiety and are easily accessible by an addition of the corresponding lithiated alkynes 5 to the aldehydes 4, leads to the tetrasubstituted alkenes 2 and 3 in good yield. The reaction produces exclusively compounds with an E double bond and additionally proceeds with good to excellent induced diastereoselectivity in the case of 1 e and 1 f. Irradiation of 2 e leads to a steady state equilibrium of the E and Z compounds in a 1:1 ratio." @default.
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• W2132877164 date "2002-01-18" @default.
• W2132877164 modified "2023-10-18" @default.
• W2132877164 title "Efficient Synthesis of Tetrasubstituted Alkenes by Allylsilane-Terminated Domino-Heck Double Cyclisation" @default.
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• W2132877164 doi "https://doi.org/10.1002/1521-3765(20020118)8:2<401::aid-chem401>3.0.co;2-c" @default.
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