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- W2132883690 abstract "Silane and disilane diluted in argon and hydrogen mixtures were pyrolyzed behind incident shock waves at temperatures ranging from 900 to 2000 K, pressures from 0.2 to 0.7 atm, and total concentration from 3 × 1016 to 1 × 1017 silicon atoms per cm3. Formation of silicon particles was monitored by the attenuation of laser beams of two different wavelengths, thereby determining particle size, number density, and fractional yield. The conversion of silane and disilane into silicon particles exhibited a pronounced maximum at about 1150 K, which was found to be affected by reaction pressure, initial reactant concentration, and addition of hydrogen. Selected silicon particle samples were examined by electron diffraction, transmission electron microscopy, and secondary ion mass spectrometry. The results indicated that the produced particles were spherical, ranging from 100 to 400 A in diameter, loosely agglomerated, and contained about 15% hydrogen on an atomic basis. A detailed chemical kinetic model was developed that describes gas-phase pyrolysis of the parent molecule and homogeneous nucleation of silicon particles by 117 elementary reactions of 42 chemical species, and coagulation of the forming particles and their growth by gas-surface deposition reactions with a method of moments. The model predictions were found to be extremely sensitive to the values of optical constants assigned to the silicon particle material." @default.
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- W2132883690 date "1996-01-01" @default.
- W2132883690 modified "2023-09-27" @default.
- W2132883690 title "Silicon Particle Formation in Pyrolysis of Silane and Disilane" @default.
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- W2132883690 doi "https://doi.org/10.1002/ijch.199600041" @default.
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