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- W2132928713 abstract "Abstract A variety of molybdenum complexes catalyze Friedel–Crafts‐type alkylation reactions of benzene derivatives with alkenes and alcohols in the presence of an organic oxidant, o ‐chloranil. The utilization of [Mo(CO) 6 ] and two equivalents of o ‐chloranil catalytically furnished the hydroarylation product of norbornene with p ‐xylene at 80 °C, whereas [Cr(CO) 6 ] and [W(CO) 6 ] failed to catalyze the same reaction, thus indicating the importance of the molybdenum source. The best results were obtained when a molybdenum(II) complex [CpMoCl(CO) 3 ] (Cp=cyclopentadienyl) was used as a precatalyst. The hydroarylation reactions also took place with styrenes, cyclohexenes, and 1‐hexene as olefin substrates. The electrophilic‐substitution mechanism was proposed on the basis of the ortho / para selectivities and the Markovnikov selectivities observed for the hydroarylation products. Our hypothesis was further corroborated by the fact that in the presence of the [CpMoCl(CO) 3 ]/ o ‐chloranil catalytic system, secondary, benzylic, or allylic alcohols participated in the alkylation of benzenes with similar selectivities." @default.
- W2132928713 created "2016-06-24" @default.
- W2132928713 creator A5002693083 @default.
- W2132928713 creator A5067407925 @default.
- W2132928713 date "2008-11-21" @default.
- W2132928713 modified "2023-10-18" @default.
- W2132928713 title "Versatile Friedel-Crafts-Type Alkylation of Benzene Derivatives Using a Molybdenum Complex/ortho-Chloranil Catalytic System" @default.
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