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- W2133037811 abstract "Abstract Reaction of lithium dimethylcuprate with a series of substituted 10-methyl-1(9)-octal-2-ones in diethyl ether give 1,4-addition products with the same ring junction stereochemistry as the parent, unsubstituted α,β-unsaturated ketone. The reactivity of the system is modified by groups positioned axially and 1,3 with respect to the β-carbon of the enone. Alkoxy substituents are generally activating, particularly if they are syn with respect to the incoming methyl group." @default.
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- W2133037811 date "1998-09-01" @default.
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- W2133037811 title "Steric and complexation effects on the 1,4-addition reaction of lithium dimethylcuprate with rigid α,β-unsaturated ketones" @default.
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- W2133037811 doi "https://doi.org/10.1016/s0040-4020(98)83052-4" @default.
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