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• W2133286329 abstract "The formation of borate esters of various mono- and di-saccharides in aqueous solution was studied by 11B and 13C NMR spectroscopy. Association constants K(B-L) at a carbohydrate-borate molar ratio of 1:1, pH 7, and 25 degrees C were determined and compared with literature values obtained from potentiometry. The association constants K(B-L) were converted into local association constants Kloc(B-L) by using the distribution of the various anomeric forms in D2O. In this way, values of Kloc(B-L) were obtained, which appear to be characteristic of the configuration concerned. They explain the favourable effect of borate in the alkaline isomerisation of lactose into lactulose. At a low molar ratio (1:3) of carbohydrate-borate, predominantly diborate esters (B-)2L were formed." @default.
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• W2133286329 date "1994-02-01" @default.
• W2133286329 modified "2023-10-09" @default.
• W2133286329 title "The structure and (local) stability constants of borate esters of mono- and di-saccharides as studied by 11B and 13C NMR spectroscopy" @default.
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• W2133286329 doi "https://doi.org/10.1016/0008-6215(94)80050-2" @default.
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