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- W2133460384 endingPage "7331" @default.
- W2133460384 startingPage "7326" @default.
- W2133460384 abstract "The incorporation of an N-heterocyclic carbene (NHC) moiety into a self-assembled MII4L6 cage framework required the NHC first to be metallated with gold(i). Bimetallic cages could then be constructed using zinc(ii) and cadmium(ii) templates, showing weak luminescence. The cages were destroyed by the addition of further gold(i) in the form of AuI(2,4,6-trimethoxybenzonitrile)2SbF6, which caused the reversibly-formed cages to disassemble and controllably release the AuI-NHC subcomponent into solution. This release in turn induced the growth of gold nanoparticles. The rate of dianiline release could be tuned by capsule design or through the addition of chemical stimuli, with different release profiles giving rise to different nanoparticle morphologies." @default.
- W2133460384 created "2016-06-24" @default.
- W2133460384 creator A5001642191 @default.
- W2133460384 creator A5017482765 @default.
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- W2133460384 creator A5034004588 @default.
- W2133460384 creator A5038924526 @default.
- W2133460384 creator A5059238305 @default.
- W2133460384 date "2015-01-01" @default.
- W2133460384 modified "2023-10-11" @default.
- W2133460384 title "AuICl-bound N-heterocyclic carbene ligands form MII4(LAuCl)6 integrally gilded cages" @default.
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- W2133460384 doi "https://doi.org/10.1039/c5sc03065j" @default.
- W2133460384 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5512534" @default.
- W2133460384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28757991" @default.