Matches in SemOpenAlex for { <https://semopenalex.org/work/W2133614745> ?p ?o ?g. }
- W2133614745 endingPage "1068" @default.
- W2133614745 startingPage "1059" @default.
- W2133614745 abstract "APR experiments have been carried out on V3+ and Cr4+ ions in Al2O3 partly to remove discrepancies in earlier measurements, and partly to provide additional information necessary for the theoretical analysis which follows. We find |G-| ∼ 45± 10 cm−1 and ∼ 160±30 cm−1 for V3+ and Cr4+ respectively. It is shown that all the data for both ions can only be explained satisfactorily if a moderately strong Jahn-Teller effect operates in the cubic 3T1, ground state of the ion. Full details are given, γ is found to be 0.14 and 0.36 for V3+ and Cr4+ respectively and important contributions from second-order Jahn-Teller effects are also present. The results also show that it is necessary to use a multimode full-lattice model of the Jahn-Teller effect as the constraints of the cluster model are broken. The implications of the proposed model on thermal conductivity, phonon spectroscopy and optical measurements are also briefly discussed. It is also pointed out that some important errors exist in the literature concerning the interpretation of experimental data for these systems." @default.
- W2133614745 created "2016-06-24" @default.
- W2133614745 creator A5023184439 @default.
- W2133614745 creator A5039579993 @default.
- W2133614745 creator A5077129692 @default.
- W2133614745 date "1976-01-01" @default.
- W2133614745 modified "2023-09-26" @default.
- W2133614745 title "Jahn-teller effects in (3d)2 ions in Al2O3" @default.
- W2133614745 cites W1611164522 @default.
- W2133614745 cites W1658874838 @default.
- W2133614745 cites W1973939141 @default.
- W2133614745 cites W1993037746 @default.
- W2133614745 cites W2006233251 @default.
- W2133614745 cites W2007846346 @default.
- W2133614745 cites W2010823955 @default.
- W2133614745 cites W2014265206 @default.
- W2133614745 cites W2014634627 @default.
- W2133614745 cites W2015024872 @default.
- W2133614745 cites W2018852400 @default.
- W2133614745 cites W2021917055 @default.
- W2133614745 cites W2023205566 @default.
- W2133614745 cites W2025900504 @default.
- W2133614745 cites W2029338306 @default.
- W2133614745 cites W2036397872 @default.
- W2133614745 cites W2042772154 @default.
- W2133614745 cites W2043805862 @default.
- W2133614745 cites W2046832968 @default.
- W2133614745 cites W2052513432 @default.
- W2133614745 cites W2063938153 @default.
- W2133614745 cites W2069744634 @default.
- W2133614745 cites W2071791578 @default.
- W2133614745 cites W2075466263 @default.
- W2133614745 cites W2083902846 @default.
- W2133614745 cites W2086732482 @default.
- W2133614745 cites W2090337846 @default.
- W2133614745 cites W2092017115 @default.
- W2133614745 cites W2111626188 @default.
- W2133614745 cites W2138540856 @default.
- W2133614745 cites W2235662740 @default.
- W2133614745 cites W2315689314 @default.
- W2133614745 cites W2317940093 @default.
- W2133614745 cites W2327116263 @default.
- W2133614745 cites W2609890098 @default.
- W2133614745 cites W2911878103 @default.
- W2133614745 cites W3010550434 @default.
- W2133614745 cites W1964966892 @default.
- W2133614745 doi "https://doi.org/10.1016/0022-3697(76)90131-1" @default.
- W2133614745 hasPublicationYear "1976" @default.
- W2133614745 type Work @default.
- W2133614745 sameAs 2133614745 @default.
- W2133614745 citedByCount "25" @default.
- W2133614745 countsByYear W21336147452013 @default.
- W2133614745 countsByYear W21336147452015 @default.
- W2133614745 crossrefType "journal-article" @default.
- W2133614745 hasAuthorship W2133614745A5023184439 @default.
- W2133614745 hasAuthorship W2133614745A5039579993 @default.
- W2133614745 hasAuthorship W2133614745A5077129692 @default.
- W2133614745 hasConcept C121332964 @default.
- W2133614745 hasConcept C121864883 @default.
- W2133614745 hasConcept C145148216 @default.
- W2133614745 hasConcept C184779094 @default.
- W2133614745 hasConcept C185592680 @default.
- W2133614745 hasConcept C24169881 @default.
- W2133614745 hasConcept C24890656 @default.
- W2133614745 hasConcept C26873012 @default.
- W2133614745 hasConcept C2781204021 @default.
- W2133614745 hasConcept C62520636 @default.
- W2133614745 hasConcept C69523127 @default.
- W2133614745 hasConcept C83981384 @default.
- W2133614745 hasConcept C97355855 @default.
- W2133614745 hasConceptScore W2133614745C121332964 @default.
- W2133614745 hasConceptScore W2133614745C121864883 @default.
- W2133614745 hasConceptScore W2133614745C145148216 @default.
- W2133614745 hasConceptScore W2133614745C184779094 @default.
- W2133614745 hasConceptScore W2133614745C185592680 @default.
- W2133614745 hasConceptScore W2133614745C24169881 @default.
- W2133614745 hasConceptScore W2133614745C24890656 @default.
- W2133614745 hasConceptScore W2133614745C26873012 @default.
- W2133614745 hasConceptScore W2133614745C2781204021 @default.
- W2133614745 hasConceptScore W2133614745C62520636 @default.
- W2133614745 hasConceptScore W2133614745C69523127 @default.
- W2133614745 hasConceptScore W2133614745C83981384 @default.
- W2133614745 hasConceptScore W2133614745C97355855 @default.
- W2133614745 hasIssue "11" @default.
- W2133614745 hasLocation W21336147451 @default.
- W2133614745 hasOpenAccess W2133614745 @default.
- W2133614745 hasPrimaryLocation W21336147451 @default.
- W2133614745 hasRelatedWork W1492945341 @default.
- W2133614745 hasRelatedWork W1974866731 @default.
- W2133614745 hasRelatedWork W1976937518 @default.
- W2133614745 hasRelatedWork W1989861026 @default.
- W2133614745 hasRelatedWork W2011751377 @default.
- W2133614745 hasRelatedWork W2038017540 @default.
- W2133614745 hasRelatedWork W2052213996 @default.
- W2133614745 hasRelatedWork W2068738674 @default.
- W2133614745 hasRelatedWork W2074873141 @default.
- W2133614745 hasRelatedWork W2317165715 @default.
- W2133614745 hasVolume "37" @default.