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• W2133744892 abstract "The syntheses of non‐electrolyte complexes of the general formula [Co(Hdmg)2(HA)X], where Hdmg˭dimethylglyoximato monoanion, HA˭glycine (Gly), Serine (Ser), Cysteine (Cys) or Cystine (Cys–Cys) and X˭Cl, Br, I, SCN are described. The structure of the complexes proposed according to elemental analyses, IR, UV‐Visible and 1H NMR spectra is pseudo-octahedral. The cyclic voltammograms in DMSO at a GC disk electrode consist of two processes (I and II) corresponding to oxidations, whereas the redox systems III and IV appear to be associated with reduction processes. The Co(II)/Co(I) redox couple is reversible for various complexes and is relatively insensitive to the axial ligand. The Co(III)/Co(II) couple depends on the axial ligation, shows chemical irreversibility and has a much slower rate of electron transfer than the Co(II)/Co(I) couple due to the strong binding of the Lewis base to the Co(III) ion." @default.
• W2133744892 created "2016-06-24" @default.
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• W2133744892 date "2003-01-03" @default.
• W2133744892 modified "2023-10-15" @default.
• W2133744892 title "Synthesis, Characterization, and Electrochemical Behavior of Mixed‐Ligand Complexes of Cobalt(III) with Dimethylglyoxime and Some Amino Acids" @default.
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• W2133744892 doi "https://doi.org/10.1081/sim-120016871" @default.
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