Matches in SemOpenAlex for { <https://semopenalex.org/work/W2133929384> ?p ?o ?g. }
- W2133929384 endingPage "736" @default.
- W2133929384 startingPage "726" @default.
- W2133929384 abstract "Abstract Electrochemical reduction of primary (1‐halodecane), secondary (2‐halohexane and cyclohexyl halide), and tertiary halides ( tert ‐butyl halide) at a silver cathode in dimethylformamide (DMF) containing 0.050 M tetramethylammonium perchlorate (TMAP) was investigated with the aid of cyclic voltammetry and controlled‐potential (bulk) electrolysis for iodides, bromides, and chlorides. Selected reductions were probed in dried DMF–TMAP and DMF containing tetra‐ n ‐hexylammonium perchlorate (THAP). Cyclic voltammograms reveal that the number of cathodic peaks and their potentials are highly dependent on the identity and position of the halogen as well as the composition of the solvent–electrolyte. Intermediates arising from bulk electrolysis of these halides at silver undergo both radical and carbanion reactions. Electrolysis products depend on the identity and position of the halogen, amount of residual water, and size of the electrolyte cation in the solvent–electrolyte. Theoretical calculations of molecular dipole moments and polarizabilities were performed and compared to experimental observations." @default.
- W2133929384 created "2016-06-24" @default.
- W2133929384 creator A5011183754 @default.
- W2133929384 creator A5045289003 @default.
- W2133929384 creator A5045669293 @default.
- W2133929384 creator A5057934743 @default.
- W2133929384 date "2015-02-11" @default.
- W2133929384 modified "2023-09-26" @default.
- W2133929384 title "Direct Reduction of Alkyl Monohalides at Silver in Dimethylformamide: Effects of Position and Identity of the Halogen" @default.
- W2133929384 cites W175618499 @default.
- W2133929384 cites W1965518932 @default.
- W2133929384 cites W1966450257 @default.
- W2133929384 cites W1971275758 @default.
- W2133929384 cites W1972035853 @default.
- W2133929384 cites W1974667766 @default.
- W2133929384 cites W1976335700 @default.
- W2133929384 cites W1978535413 @default.
- W2133929384 cites W1981836513 @default.
- W2133929384 cites W1985684227 @default.
- W2133929384 cites W1998627507 @default.
- W2133929384 cites W2000385348 @default.
- W2133929384 cites W2000494190 @default.
- W2133929384 cites W2002276120 @default.
- W2133929384 cites W2005053866 @default.
- W2133929384 cites W2006039476 @default.
- W2133929384 cites W2007692686 @default.
- W2133929384 cites W2009358910 @default.
- W2133929384 cites W2010601024 @default.
- W2133929384 cites W2011143390 @default.
- W2133929384 cites W2011379859 @default.
- W2133929384 cites W2018690178 @default.
- W2133929384 cites W2018961629 @default.
- W2133929384 cites W2019212705 @default.
- W2133929384 cites W2020015611 @default.
- W2133929384 cites W2024958075 @default.
- W2133929384 cites W2025186634 @default.
- W2133929384 cites W2026184529 @default.
- W2133929384 cites W2030982774 @default.
- W2133929384 cites W2037223803 @default.
- W2133929384 cites W2039366910 @default.
- W2133929384 cites W2040244058 @default.
- W2133929384 cites W2041461684 @default.
- W2133929384 cites W2042422866 @default.
- W2133929384 cites W2044349150 @default.
- W2133929384 cites W2046256638 @default.
- W2133929384 cites W2047032736 @default.
- W2133929384 cites W2048804401 @default.
- W2133929384 cites W2048926658 @default.
- W2133929384 cites W2054084739 @default.
- W2133929384 cites W2060621817 @default.
- W2133929384 cites W2063911511 @default.
- W2133929384 cites W2064015613 @default.
- W2133929384 cites W2064536747 @default.
- W2133929384 cites W2065118602 @default.
- W2133929384 cites W2067273264 @default.
- W2133929384 cites W2068750325 @default.
- W2133929384 cites W2071449196 @default.
- W2133929384 cites W2072085374 @default.
- W2133929384 cites W2074140475 @default.
- W2133929384 cites W2076840339 @default.
- W2133929384 cites W2077089876 @default.
- W2133929384 cites W2077805528 @default.
- W2133929384 cites W2083434668 @default.
- W2133929384 cites W2084261650 @default.
- W2133929384 cites W2086399903 @default.
- W2133929384 cites W2091939163 @default.
- W2133929384 cites W2092117534 @default.
- W2133929384 cites W2093802319 @default.
- W2133929384 cites W2099733231 @default.
- W2133929384 cites W2116510553 @default.
- W2133929384 cites W2159812992 @default.
- W2133929384 cites W2164252504 @default.
- W2133929384 cites W2217446705 @default.
- W2133929384 cites W2312795741 @default.
- W2133929384 cites W2330409579 @default.
- W2133929384 cites W2950289640 @default.
- W2133929384 doi "https://doi.org/10.1002/celc.201402410" @default.
- W2133929384 hasPublicationYear "2015" @default.
- W2133929384 type Work @default.
- W2133929384 sameAs 2133929384 @default.
- W2133929384 citedByCount "13" @default.
- W2133929384 countsByYear W21339293842015 @default.
- W2133929384 countsByYear W21339293842016 @default.
- W2133929384 countsByYear W21339293842017 @default.
- W2133929384 countsByYear W21339293842019 @default.
- W2133929384 countsByYear W21339293842020 @default.
- W2133929384 countsByYear W21339293842021 @default.
- W2133929384 countsByYear W21339293842023 @default.
- W2133929384 crossrefType "journal-article" @default.
- W2133929384 hasAuthorship W2133929384A5011183754 @default.
- W2133929384 hasAuthorship W2133929384A5045289003 @default.
- W2133929384 hasAuthorship W2133929384A5045669293 @default.
- W2133929384 hasAuthorship W2133929384A5057934743 @default.
- W2133929384 hasBestOaLocation W21339293841 @default.
- W2133929384 hasConcept C145148216 @default.
- W2133929384 hasConcept C147789679 @default.
- W2133929384 hasConcept C163127949 @default.
- W2133929384 hasConcept C171560689 @default.