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- W2133971479 abstract "Abstract The terdentate ligand 3 (LH, 2‐formylpyridine 4‐thiosemicarbazone) forms with Fe II and Ni II 2:1 complexes of octahedral geometry of formula [M II (LH) 2 ] 2+ . X‐ray diffraction studies have shown that in both complexes the thiourea moieties of the coordinated thiosemicarbazones are exposed to the outside and are prone to establish hydrogen‐bonding bifurcate interactions with oxoanions. However, spectrophotometric studies in CHCl 3 solution have shown that only the poorly basic NO 3 − ion is able to form authentic hydrogen‐bond complexes with thiourea subunits, whereas all the other investigated anions (CH 3 COO − , NO 2 − , F − ) induce deprotonation of the N‐H fragment. The extreme enhancement of the thiourea acidity is based on the coordinative interaction of the sulphur atom with the metal, which stabilises the thiolate form, and it is much higher than that exerted by any other covalently linked electron‐withdrawing substituent, for example, NO 2 ." @default.
- W2133971479 created "2016-06-24" @default.
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- W2133971479 date "2008-10-21" @default.
- W2133971479 modified "2023-09-30" @default.
- W2133971479 title "Metal-Controlled Anion-Binding Tendencies of the Thiourea Unit of Thiosemicarbazones" @default.
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- W2133971479 doi "https://doi.org/10.1002/chem.200800801" @default.
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