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- W2134112869 abstract "5-Methyl-1,3-cyclohexandion wird von Benzyloxyessigsäure-imidazolid zu 2b C-acyliert, das mit Hydrazinen die 1,5,6,7-Tetrahydro-4H-indazol-4-one 3a–d ergibt. Deren Hydrogenolyse führt zu den Titelverbindungen 4a–d. Das Acetat 5a aus 3d wird zu 5b hydrogenolysiert und weiter in das Carbamat 6 umgewandelt. Enehydrazines, 32. — An Access to 3-Hydroxymethyl-1,5,6,7-tetrahydro-4H-indazol-4-ones 5-Methyl-1,3-cyclohexanedione is C-acylated with benzyloxyacetimidazolide to yield 2b which with hydrazines gives the 1,5,6,7-tetrahydro-4H-indazol-4-ones 3a–d. Hydrogenolysis leads to the title compounds 4a–d. The acetate 5a from 3d is hydrogenolyzed to give 5b and is further transformed into the carbamate 6." @default.
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- W2134112869 date "1982-10-18" @default.
- W2134112869 modified "2023-10-17" @default.
- W2134112869 title "Enhydrazine, 32. Ein Zugang zu 3-Hydroxymethyl-1,5,6,7-tetrahydro-4H-indazol-4-onen" @default.
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- W2134112869 doi "https://doi.org/10.1002/jlac.198219821010" @default.
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