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• W2134201422 endingPage "5674" @default.
• W2134201422 startingPage "5668" @default.
• W2134201422 abstract "Abstract The treatment of [Mo 2 (pyphos) 4 ] ( 1 ) (pyphos = 6‐diphenylphosphanyl‐2‐pyridonate) with [Cu(NCCH 3 ) 4 ](PF 6 ) in CH 2 Cl 2 and CH 3 CN mixed solvent (1:5 v/v) led to the formation of a linear tetranuclear cluster, cis ‐[Mo 2 {Cu(NCCH 3 ) 2 } 2 ][(pyphos) 4 ](PF 6 ) 2 ( cis ‐ 2a‐PF 6 ), as a thermodynamic product that was structurally characterized as a tetrakis[3,5‐bis(trifluoromethyl)phenylborate] salt ( cis‐ 2a‐BArF ). In the solid‐state structure of cis ‐ 2a‐BArF , the Mo 2 core was bridged by two O–N chelating pyphos ligands in a cis fashion, in sharp contrast to a trans fashion in 1 . The trans isomer ( trans ‐ 2b‐PF 6 ) was isolated from a noncoordinating solvent such as CH 2 Cl 2 and structurally characterized. The transformation from trans ‐ 2b to cis ‐ 2a proceeded in acetonitrile by means of an intramolecular rearrangement of the paddlewheel Mo 2 core upon dissolution in acetonitrile, in which the coordinating solvent stabilizes the transient, coordinatively unsaturated Mo 2 core upon the release of the pyridonate moiety from the Mo 2 core; whereas the reverse reaction did not occur under any trial conditions. A further substitution reaction at the Cu center of cis ‐ 2a‐PF 6 and trans ‐ 2b‐PF 6 with Et 4 NCl afforded cis ‐ 3a and trans ‐ 3b , respectively, which have the molecular formula [Mo 2 (pyphos) 4 Cu 2 (Cl) 2 ]. Compounds trans ‐ 3a and cis ‐ 3b do not show any solvent‐dependent interconversion phenomena by changing the solvent." @default.
• W2134201422 created "2016-06-24" @default.
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• W2134201422 creator A5029319949 @default.
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• W2134201422 date "2010-11-22" @default.
• W2134201422 modified "2023-10-12" @default.
• W2134201422 title "Solvent‐Dependent <i>cis</i> / <i>trans</i> Isomerism at the Paddlewheel Mo ₂ Core of Linear Tetranuclear Clusters of Mo ^II and Cu ^I Supported by 6‐(Diphenylphosphanyl)pyridin‐2‐olate (pyphos)" @default.
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• W2134201422 doi "https://doi.org/10.1002/ejic.201000896" @default.
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