Matches in SemOpenAlex for { <https://semopenalex.org/work/W2134263086> ?p ?o ?g. }
- W2134263086 endingPage "4773" @default.
- W2134263086 startingPage "4773" @default.
- W2134263086 abstract "We have obtained high resolution, partially rotationally resolved, jet-cooled cavity ringdown spectra of the origin band of the A<--X electronic transition of two of the five conformers (G(1)G(2) and G(1)T(2)) of the normal propyl peroxy radical, C(3)H(7)O(2), as well as the G conformer of the iso-propyl peroxy radical isomer. This transition, located in the near infrared, was studied using a narrow band laser source (less than or approximately 250 MHz) and a supersonic slit-jet expansion coupled with an electric discharge allowing us to obtain rotational temperatures of about 15 K. All three spectra have been successfully fitted using an evolutionary algorithm approach with a Hamiltonian including rotational and spin-rotational terms. Excellent agreement with the experimental spectra was obtained by fitting seven molecular parameters in each of the ground and the first excited electronic states as well as the band origin of the electronic transition. These parameters are compared with the results from electronic structure calculations. This analysis confirms unambiguously the previous room-temperature conformer assignments that were based upon quantum chemistry calculations." @default.
- W2134263086 created "2016-06-24" @default.
- W2134263086 creator A5000410636 @default.
- W2134263086 creator A5035467934 @default.
- W2134263086 creator A5061947031 @default.
- W2134263086 creator A5068489536 @default.
- W2134263086 date "2010-01-01" @default.
- W2134263086 modified "2023-09-24" @default.
- W2134263086 title "High-resolution cavity ringdown spectroscopy of the jet-cooled propyl peroxy radical C3H7O2" @default.
- W2134263086 cites W104504545 @default.
- W2134263086 cites W1556552051 @default.
- W2134263086 cites W1576617753 @default.
- W2134263086 cites W1964822420 @default.
- W2134263086 cites W1969122076 @default.
- W2134263086 cites W1971672497 @default.
- W2134263086 cites W1977892342 @default.
- W2134263086 cites W1980697380 @default.
- W2134263086 cites W1980867357 @default.
- W2134263086 cites W1982876330 @default.
- W2134263086 cites W1996404225 @default.
- W2134263086 cites W1996710067 @default.
- W2134263086 cites W1999837123 @default.
- W2134263086 cites W2002968386 @default.
- W2134263086 cites W2008714374 @default.
- W2134263086 cites W2016909189 @default.
- W2134263086 cites W2030702247 @default.
- W2134263086 cites W2039909073 @default.
- W2134263086 cites W2041945998 @default.
- W2134263086 cites W2042273588 @default.
- W2134263086 cites W2048998010 @default.
- W2134263086 cites W2056831706 @default.
- W2134263086 cites W2057778685 @default.
- W2134263086 cites W2059400570 @default.
- W2134263086 cites W2063799040 @default.
- W2134263086 cites W2067375542 @default.
- W2134263086 cites W2071799644 @default.
- W2134263086 cites W2072071104 @default.
- W2134263086 cites W2072278001 @default.
- W2134263086 cites W2084099103 @default.
- W2134263086 cites W2100447714 @default.
- W2134263086 cites W2109821487 @default.
- W2134263086 cites W2112036188 @default.
- W2134263086 cites W2131185038 @default.
- W2134263086 cites W2141587065 @default.
- W2134263086 cites W2146502820 @default.
- W2134263086 cites W2148909207 @default.
- W2134263086 cites W2156504252 @default.
- W2134263086 cites W2162290298 @default.
- W2134263086 cites W4211105962 @default.
- W2134263086 cites W90314207 @default.
- W2134263086 doi "https://doi.org/10.1039/b924323b" @default.
- W2134263086 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20428558" @default.
- W2134263086 hasPublicationYear "2010" @default.
- W2134263086 type Work @default.
- W2134263086 sameAs 2134263086 @default.
- W2134263086 citedByCount "16" @default.
- W2134263086 countsByYear W21342630862013 @default.
- W2134263086 countsByYear W21342630862014 @default.
- W2134263086 countsByYear W21342630862015 @default.
- W2134263086 countsByYear W21342630862016 @default.
- W2134263086 countsByYear W21342630862017 @default.
- W2134263086 countsByYear W21342630862019 @default.
- W2134263086 countsByYear W21342630862020 @default.
- W2134263086 countsByYear W21342630862021 @default.
- W2134263086 crossrefType "journal-article" @default.
- W2134263086 hasAuthorship W2134263086A5000410636 @default.
- W2134263086 hasAuthorship W2134263086A5035467934 @default.
- W2134263086 hasAuthorship W2134263086A5061947031 @default.
- W2134263086 hasAuthorship W2134263086A5068489536 @default.
- W2134263086 hasConcept C119947313 @default.
- W2134263086 hasConcept C121332964 @default.
- W2134263086 hasConcept C1276947 @default.
- W2134263086 hasConcept C178790620 @default.
- W2134263086 hasConcept C181500209 @default.
- W2134263086 hasConcept C184779094 @default.
- W2134263086 hasConcept C185592680 @default.
- W2134263086 hasConcept C18705241 @default.
- W2134263086 hasConcept C19329426 @default.
- W2134263086 hasConcept C21074235 @default.
- W2134263086 hasConcept C31100168 @default.
- W2134263086 hasConcept C32891209 @default.
- W2134263086 hasConcept C32909587 @default.
- W2134263086 hasConcept C41999313 @default.
- W2134263086 hasConcept C4839761 @default.
- W2134263086 hasConcept C62520636 @default.
- W2134263086 hasConcept C97355855 @default.
- W2134263086 hasConceptScore W2134263086C119947313 @default.
- W2134263086 hasConceptScore W2134263086C121332964 @default.
- W2134263086 hasConceptScore W2134263086C1276947 @default.
- W2134263086 hasConceptScore W2134263086C178790620 @default.
- W2134263086 hasConceptScore W2134263086C181500209 @default.
- W2134263086 hasConceptScore W2134263086C184779094 @default.
- W2134263086 hasConceptScore W2134263086C185592680 @default.
- W2134263086 hasConceptScore W2134263086C18705241 @default.
- W2134263086 hasConceptScore W2134263086C19329426 @default.
- W2134263086 hasConceptScore W2134263086C21074235 @default.
- W2134263086 hasConceptScore W2134263086C31100168 @default.
- W2134263086 hasConceptScore W2134263086C32891209 @default.