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- W2134313385 abstract "1 The equilibrium between the two tautomeric conjugate acids of 4-dimethyl-amino-azobenzene derivatives is a function of the concentration and the ionic strength of the solution. 2 The individual acidity constants of these two tautomeric conjugate acids have been correlated with the Hammett δϱ-relationship. 3 It can be shown that the ammonium form of the first conjugate acid of 4-dimethylamino-azobenzene derivatives is more aggregated than the azonium form. 4 The δϱ-relationships demonstrate that enhanced mesomeric interaction occurs between a -M substituent in the 4′-position and the 4-dimethylamino group, but not with the lone pair of electrons on the β-azo nitrogen atom." @default.
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- W2134313385 date "1962-01-01" @default.
- W2134313385 modified "2023-10-17" @default.
- W2134313385 title "Assoziation bei Azoverbindungen II: Einfluss der Assoziation auf das tautomere Gleichgewicht von 4-Dimethylamino-azobenzol-Derivaten" @default.
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- W2134313385 doi "https://doi.org/10.1002/hlca.19620450621" @default.
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