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- W2134351959 abstract "Nanocrystalline ZnFe2O4 spinel powders are synthesized by high-energy ball milling, starting from a powder mixture of hematite (α-Fe2O3) and zincite (ZnO). The millings are performed under air using hardened steel vials and balls. X-ray diffraction and Mössbauer spectrometry are used to characterize the powders. A spinel phase begins to appear after 3 h of milling and the synthesis is achieved after 9 h. Phase transformation is accompanied by a contamination due to iron coming from the milling tools. A redox reaction is also observed between Fe(III) and metallic iron during milling, leading to a spinel phase containing some Fe(II). The mechanism for the appearance of this phase is studied: ZnO seems to have a non-negligeable influence on the synthesis, by creating an intermediate wüstite-type phase solid solution with FeO." @default.
- W2134351959 created "2016-06-24" @default.
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- W2134351959 date "2005-11-01" @default.
- W2134351959 modified "2023-10-14" @default.
- W2134351959 title "Mechanosynthesis of zinc ferrite in hardened steel vials: Influence of ZnO on the appearance of Fe(II)" @default.
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- W2134351959 doi "https://doi.org/10.1016/j.jssc.2005.07.033" @default.
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