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- W2134392938 abstract "Multiply bonded organometallic complexes Re2(μ-Cl)(μ-η2-HCCH)Cl4(μ-dppm)2 (2) and Re2(μ-Cl)(μ-CCH2CH3)Cl4(μ-dppm)2 (3) are formed upon refluxing Re2(μ-O2CCH3)Cl4(μ-dppm)2 (1) with HO2CCCCO2H and CH3CCCO2H, respectively; these reactions are believed to proceed via the in situ formation of the corresponding metal alkynoates and the crystal structures of 2 and 3 show that the Re–Re distances of 2.6567(5) and 2.5277(6) Å are in accord with Re–Re bond orders of 1.5 and 2, respectively." @default.
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- W2134392938 date "2001-01-01" @default.
- W2134392938 modified "2023-09-23" @default.
- W2134392938 title "Decarboxylation reactions of alkyne-carboxylic acids as a route to multiply bonded [Re2]n+ μ-alkyne and μ-carbyne complexes" @default.
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- W2134392938 doi "https://doi.org/10.1039/b008265l" @default.
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