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• W2134401568 abstract "In our search to establish a reference .OH production system with respect to which the reactivity of copper(II) complexes could then be tested, the influence of free Cu2+ ions on the Cu+/H2O2 reaction has been investigated. This influence depends on the CCu2+/CCu+ ratio. At low Cu2+ concentrations, .OH damage to various detector molecules decreases with increasing Cu2+ concentrations until CCu2+/CCu+ reaches unity. Above this value, .OH damage increases sharply until CCu2+/CCu+ becomes equal to 5 with salicylate and 2 with deoxyribose, ratios for which the protective effect of Cu2+ cancels. Finally, at higher concentrations, Cu2+ ions logically add their own .OH production to that normally expected from Cu+ ions. The possible origin of this unprecedented alternate effect has been discussed. The possible influence of Cu+ ions on the generation of .OH radicals by water gamma radiolysis has also been tested and, as already established for Cu2+ in a previous work, shown to be nonexistent. This definitely confirms that either form of ionised copper cannot scavenge .OH radicals in the absence of a ligand." @default.
• W2134401568 created "2016-06-24" @default.
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• W2134401568 date "1994-01-01" @default.
• W2134401568 modified "2023-10-01" @default.
• W2134401568 title "Copper-Ligand Interactions and Physiological free Radical Processes. Part 2. Influence of Cu2+Ions on Cu+-Driven Oh Generation and Comparison with Their Effects on Fe2+-Driven Oh Production" @default.
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• W2134401568 doi "https://doi.org/10.3109/10715769409147517" @default.
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