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- W2134418000 abstract "How does a metal enzyme reduce nitrate to ammonia? Stepwise and clear transformations of nitrogen compounds in the coordination spheres of transition metals are of fundamental importance for the elucidation of such reactions of the nitrogen cycle. Since the formation of the energetically most favorable N2 molecule must be avoided, the reduction of NO to NH2OH step is especially critical. Such a reaction has now been accomplished in THF at room temperature (1 → 2). The product 2 forms configurational isomers." @default.
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- W2134418000 date "1988-09-01" @default.
- W2134418000 modified "2023-10-02" @default.
- W2134418000 title "Transformation of ?1-Nitrosyl to ?2-Hydroxylaminyl Ligands in the Reduction of [Mo(NO)2(?S4?)] to [Mo(?2-NH2O)(NO)(?S4?)]: A Model Reaction for a Partial Step in the Enzymatic NO3??NH3 Conversion" @default.
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- W2134418000 doi "https://doi.org/10.1002/anie.198811641" @default.
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