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• W2134431548 abstract "The ability of the equatorial C-H bonds to form C-H—O hydrogen bonds was studied by measuring the high-pressure Raman spectra. We have investigated the effect of pressure versus C-H—O interactions in 1,3-dioxane/D2O mixtures. Dilution of 1,3-dioxane leads to a shift of the C-H signals to higher frequencies under ambient pressure. Based on the pressure-dependence of the Raman spectra, we have found that the equatorial C-H groups of 1,3-dioxane displays a remarkably different ability to serve as the weak hydrogen bond donors in comparison to the axial C-H of 1,3-dioxane. The new Raman spectral features observed under high pressure may arise from the combined effect of hydrogen-bond network changes, hydrogen bond-like C-H—O interactions formation, cluster size changes, etc. This finding may be important to diastereo- and enantioselective synthesis." @default.
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• W2134431548 date "2005-08-01" @default.
• W2134431548 modified "2023-09-25" @default.
• W2134431548 title "Intermolecular Hydrogen Bonding and Structures in 1,3-Dioxane/D2O Mixtures Studied by High-Pressure Raman Spectroscopy" @default.
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• W2134431548 doi "https://doi.org/10.1002/jccs.200500089" @default.
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