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- W2134507593 abstract "Abstract Two phosphoramidite derivatives, 1 and 2 , each bearing two orthogonal functions: alkyne/thioacetyl or alkyne/tosyl, respectively, were synthesized and used to generate heteroglyco 5′‐oligonucleotide conjugates. After coupling, the first conjugation was performed using CuAAC on solid support with an azide‐bearing carbohydrate. For 1 , the second conjugation was performed in solution by a thiol “click” reaction using a bromoacetamide galactoside, whereas for 2 , the tosyl group was converted into an azide and a second CuAAC was applied on solid support. Accordingly, a deoxycholic‐centered heteroglycocluster exhibiting two D ‐galactose and two L ‐fucose motifs, conjugated to an oligonucleotide, was successfully synthesized." @default.
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- W2134507593 date "2015-03-17" @default.
- W2134507593 modified "2023-10-03" @default.
- W2134507593 title "Hetero-Click Conjugation of Oligonucleotides with Glycosides Using Bifunctional Phosphoramidites" @default.
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- W2134507593 doi "https://doi.org/10.1002/ejoc.201500165" @default.
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