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- W2134558705 abstract "[88215-41-2] C6H4AuCl2NO2 (MW 389.97)InChI = 1S/C6H5NO2.Au.2ClH/c8-6(9)5-3-1-2-4-7-5;;;/h1-4H,(H,8,9);;2*1H/q;+3;;/p-3InChIKey = PKAWSKSRAJXTIH-UHFFFAOYSA-K(reagent used for activation of alkynes/allenes toword nucleophilic attack)Physical Data: mp 166 °C.1Solubility: soluble in most polar organic solvents including CH2Cl2, THF, and EtOAc, but not in hexanes, diethyl ether, and water.Form Supplied in: pale yellow crystalline solid, not commercially available.Preparative Methods: an aqueous solution of pyridine-2-carboxylic acid was slowly added to an aqueous solution of KAuCl4 (1 equiv) at room temperature, and the initial solid precipitate was filtered off. The second crop of pale yellow solid precipitates after cooling in a refrigerator overnight was obtained as product after filtration.1 Better yield can be obtained when excess pyridine-2-carboxylic acid is used.2Handling, Storage, and Precautions: shelf-stable, not hygroscopic." @default.
- W2134558705 created "2016-06-24" @default.
- W2134558705 creator A5023271899 @default.
- W2134558705 date "2009-03-15" @default.
- W2134558705 modified "2023-09-25" @default.
- W2134558705 title "Dichloro(pyridine-2-carboxylato)-gold(III)" @default.
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- W2134558705 doi "https://doi.org/10.1002/047084289x.rn01004" @default.
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