Matches in SemOpenAlex for { <https://semopenalex.org/work/W2134561959> ?p ?o ?g. }
- W2134561959 endingPage "5618" @default.
- W2134561959 startingPage "5613" @default.
- W2134561959 abstract "Abstract The two‐step spin crossover in mononuclear iron(III) complex [Fe(salpm) 2 ]ClO 4 ⋅ 0.5 EtOH ( 1 ) is shown to be accompanied by a structural phase transition as concluded from 57 Fe Mössbauer spectroscopy and single crystal X‐ray diffraction, with spin‐state ordering on just one of two sub‐lattices in the intermediate magnetic and structural phase. The complex also exhibits thermal‐ and light‐induced spin‐state trapping (TIESST and LIESST), and relaxation from the LIESST and TIESST excited states occurs via the broken symmetry intermediate phase. Two relaxation events are evident in both experiments, that is, two T(LIESST) and two T(TIESST) values are recorded. The change in symmetry which accompanies the TIESST effect was followed in real time using single crystal diffraction. After flash freezing at 15 K the crystal was warmed to 40 K at which temperature superstructure reflections were observed to appear and disappear within a 10 000 s time range. In the frame of the international year of crystallography, these results illustrate how X‐ray diffraction makes it possible to understand complex ordering phenomena." @default.
- W2134561959 created "2016-06-24" @default.
- W2134561959 creator A5001529398 @default.
- W2134561959 creator A5021549296 @default.
- W2134561959 creator A5044632291 @default.
- W2134561959 creator A5048552245 @default.
- W2134561959 creator A5049359044 @default.
- W2134561959 creator A5052695789 @default.
- W2134561959 creator A5054401382 @default.
- W2134561959 creator A5070995922 @default.
- W2134561959 creator A5075728529 @default.
- W2134561959 creator A5078415011 @default.
- W2134561959 date "2014-03-27" @default.
- W2134561959 modified "2023-10-16" @default.
- W2134561959 title "Spin-State Ordering on One Sub-lattice of a Mononuclear Iron(III) Spin Crossover Complex Exhibiting LIESST and TIESST" @default.
- W2134561959 cites W1575648836 @default.
- W2134561959 cites W1938614094 @default.
- W2134561959 cites W1966555688 @default.
- W2134561959 cites W1975319963 @default.
- W2134561959 cites W1976479988 @default.
- W2134561959 cites W1980455191 @default.
- W2134561959 cites W1985781915 @default.
- W2134561959 cites W1990631154 @default.
- W2134561959 cites W1991451238 @default.
- W2134561959 cites W1999335283 @default.
- W2134561959 cites W1999998933 @default.
- W2134561959 cites W2003298677 @default.
- W2134561959 cites W2005642160 @default.
- W2134561959 cites W2010315244 @default.
- W2134561959 cites W2015974803 @default.
- W2134561959 cites W2018107847 @default.
- W2134561959 cites W2018756890 @default.
- W2134561959 cites W2019644501 @default.
- W2134561959 cites W2020696334 @default.
- W2134561959 cites W2021366185 @default.
- W2134561959 cites W2028243009 @default.
- W2134561959 cites W2029881156 @default.
- W2134561959 cites W2035359633 @default.
- W2134561959 cites W2037867565 @default.
- W2134561959 cites W2041856631 @default.
- W2134561959 cites W2042037132 @default.
- W2134561959 cites W2045270719 @default.
- W2134561959 cites W2047287764 @default.
- W2134561959 cites W2050312377 @default.
- W2134561959 cites W2064311755 @default.
- W2134561959 cites W2069509680 @default.
- W2134561959 cites W2069587910 @default.
- W2134561959 cites W2071748478 @default.
- W2134561959 cites W2072902383 @default.
- W2134561959 cites W2078071000 @default.
- W2134561959 cites W2091992259 @default.
- W2134561959 cites W2096216193 @default.
- W2134561959 cites W2101349242 @default.
- W2134561959 cites W2104649441 @default.
- W2134561959 cites W2106096919 @default.
- W2134561959 cites W2113131326 @default.
- W2134561959 cites W2114676525 @default.
- W2134561959 cites W2120938115 @default.
- W2134561959 cites W2123521708 @default.
- W2134561959 cites W2126705766 @default.
- W2134561959 cites W2128804770 @default.
- W2134561959 cites W2130670219 @default.
- W2134561959 cites W2132552867 @default.
- W2134561959 cites W2146053166 @default.
- W2134561959 cites W2147690611 @default.
- W2134561959 cites W2159042504 @default.
- W2134561959 cites W2161133220 @default.
- W2134561959 cites W2163185964 @default.
- W2134561959 cites W2165734921 @default.
- W2134561959 cites W2165788817 @default.
- W2134561959 cites W2168806775 @default.
- W2134561959 cites W2170309964 @default.
- W2134561959 cites W2173576669 @default.
- W2134561959 cites W2312589207 @default.
- W2134561959 cites W2315106869 @default.
- W2134561959 cites W2327284422 @default.
- W2134561959 cites W2334271474 @default.
- W2134561959 cites W2950525462 @default.
- W2134561959 cites W4232162804 @default.
- W2134561959 cites W4232556585 @default.
- W2134561959 cites W4249373410 @default.
- W2134561959 cites W4249939793 @default.
- W2134561959 cites W951769768 @default.
- W2134561959 doi "https://doi.org/10.1002/chem.201400286" @default.
- W2134561959 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24677415" @default.
- W2134561959 hasPublicationYear "2014" @default.
- W2134561959 type Work @default.
- W2134561959 sameAs 2134561959 @default.
- W2134561959 citedByCount "81" @default.
- W2134561959 countsByYear W21345619592014 @default.
- W2134561959 countsByYear W21345619592015 @default.
- W2134561959 countsByYear W21345619592016 @default.
- W2134561959 countsByYear W21345619592017 @default.
- W2134561959 countsByYear W21345619592018 @default.
- W2134561959 countsByYear W21345619592019 @default.
- W2134561959 countsByYear W21345619592020 @default.
- W2134561959 countsByYear W21345619592021 @default.
- W2134561959 countsByYear W21345619592022 @default.