Matches in SemOpenAlex for { <https://semopenalex.org/work/W2134653181> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2134653181 endingPage "8193" @default.
- W2134653181 startingPage "8191" @default.
- W2134653181 abstract "Deuteration of Zr2Cu leads to a reconstruction of its MoSi2-type metal atom arrangement. While the tetragonal alloy contains isolated copper atoms (Cu-Cu = 3.22 angstroms) in a cubic zirconium atom environment, the monoclinic deuteride Zr2CuD4.71 contains Cu2 dumbbells (Cu-Cu = 2.39 angstroms), of which each copper atom has a trigonal-prismatic zirconium atom environment. Deuterium occupies five sites, of which four have tetrahedral metal configurations (two Zr4-type and two Zr3Cu-type) and are fully occupied while one has a trigonal-bipyramidal metal configuration (Zr3Cu2-type) and is partially occupied (71%). Copper is bonded to four deuterium atoms in a saddle-like configuration (Cu-D = 1.73-1.87 angstroms). Two of the ligands connect copper in a nearly linear Cu-D-Cu arrangement to partially interrupted dimeric [Cu2D6](n)() ribbons running perpendicular to the Cu2 dumbbell direction. At the upper phase limit, the ribbons are presumably no longer interrupted and the deuteride can be described by the limiting ionic formula 2Zr2+[Cu(+)D3](2-)2D-." @default.
- W2134653181 created "2016-06-24" @default.
- W2134653181 creator A5026570151 @default.
- W2134653181 creator A5055853145 @default.
- W2134653181 date "2005-11-01" @default.
- W2134653181 modified "2023-09-25" @default.
- W2134653181 title "Deuterium-Induced Copper Pairing in Zr2CuD∼5" @default.
- W2134653181 cites W1650224654 @default.
- W2134653181 cites W1803680424 @default.
- W2134653181 cites W1998289748 @default.
- W2134653181 cites W2002471089 @default.
- W2134653181 cites W2018264533 @default.
- W2134653181 cites W2021746019 @default.
- W2134653181 cites W2022857645 @default.
- W2134653181 cites W2026809737 @default.
- W2134653181 cites W2037763919 @default.
- W2134653181 cites W2062721498 @default.
- W2134653181 cites W2065089908 @default.
- W2134653181 cites W2068754430 @default.
- W2134653181 cites W2071606530 @default.
- W2134653181 cites W2092355288 @default.
- W2134653181 cites W2095304760 @default.
- W2134653181 cites W2116790795 @default.
- W2134653181 cites W2134702028 @default.
- W2134653181 cites W2145127643 @default.
- W2134653181 cites W2167383445 @default.
- W2134653181 cites W2243663245 @default.
- W2134653181 cites W2951073645 @default.
- W2134653181 cites W78835848 @default.
- W2134653181 cites W2050575726 @default.
- W2134653181 doi "https://doi.org/10.1021/ic0514039" @default.
- W2134653181 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16270953" @default.
- W2134653181 hasPublicationYear "2005" @default.
- W2134653181 type Work @default.
- W2134653181 sameAs 2134653181 @default.
- W2134653181 citedByCount "5" @default.
- W2134653181 countsByYear W21346531812013 @default.
- W2134653181 countsByYear W21346531812014 @default.
- W2134653181 crossrefType "journal-article" @default.
- W2134653181 hasAuthorship W2134653181A5026570151 @default.
- W2134653181 hasAuthorship W2134653181A5055853145 @default.
- W2134653181 hasConcept C111592845 @default.
- W2134653181 hasConcept C115624301 @default.
- W2134653181 hasConcept C149635348 @default.
- W2134653181 hasConcept C170751736 @default.
- W2134653181 hasConcept C178790620 @default.
- W2134653181 hasConcept C179104552 @default.
- W2134653181 hasConcept C185592680 @default.
- W2134653181 hasConcept C41008148 @default.
- W2134653181 hasConcept C534791751 @default.
- W2134653181 hasConcept C544153396 @default.
- W2134653181 hasConcept C544778455 @default.
- W2134653181 hasConcept C58312451 @default.
- W2134653181 hasConcept C61276311 @default.
- W2134653181 hasConcept C8010536 @default.
- W2134653181 hasConceptScore W2134653181C111592845 @default.
- W2134653181 hasConceptScore W2134653181C115624301 @default.
- W2134653181 hasConceptScore W2134653181C149635348 @default.
- W2134653181 hasConceptScore W2134653181C170751736 @default.
- W2134653181 hasConceptScore W2134653181C178790620 @default.
- W2134653181 hasConceptScore W2134653181C179104552 @default.
- W2134653181 hasConceptScore W2134653181C185592680 @default.
- W2134653181 hasConceptScore W2134653181C41008148 @default.
- W2134653181 hasConceptScore W2134653181C534791751 @default.
- W2134653181 hasConceptScore W2134653181C544153396 @default.
- W2134653181 hasConceptScore W2134653181C544778455 @default.
- W2134653181 hasConceptScore W2134653181C58312451 @default.
- W2134653181 hasConceptScore W2134653181C61276311 @default.
- W2134653181 hasConceptScore W2134653181C8010536 @default.
- W2134653181 hasIssue "23" @default.
- W2134653181 hasLocation W21346531811 @default.
- W2134653181 hasLocation W21346531812 @default.
- W2134653181 hasOpenAccess W2134653181 @default.
- W2134653181 hasPrimaryLocation W21346531811 @default.
- W2134653181 hasRelatedWork W1975746421 @default.
- W2134653181 hasRelatedWork W1979358532 @default.
- W2134653181 hasRelatedWork W1999828662 @default.
- W2134653181 hasRelatedWork W2314729056 @default.
- W2134653181 hasRelatedWork W2317441903 @default.
- W2134653181 hasRelatedWork W2320987880 @default.
- W2134653181 hasRelatedWork W2378479697 @default.
- W2134653181 hasRelatedWork W2384288356 @default.
- W2134653181 hasRelatedWork W2519202341 @default.
- W2134653181 hasRelatedWork W3149325189 @default.
- W2134653181 hasVolume "44" @default.
- W2134653181 isParatext "false" @default.
- W2134653181 isRetracted "false" @default.
- W2134653181 magId "2134653181" @default.
- W2134653181 workType "article" @default.