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• W2134662180 abstract "A general model to calculate the structure of a smectic to nematic-like order in polymer systems is proposed. The model is limited to well-aligned molecules with respect to each other. It is especially suited for systems where the packing between neighboring chains is described by liquid-like disorder with axial registration in the chain-axis direction. In such a case the diffraction pattern from the oriented structure exhibits broad liquid-like reflections on the equatorial but sharper reflections on the layer lines. An Ornstein–Zernike approach is adopted to calculate the inter-chain packing and inter-chain registration, where the direct correlation function of packing and registration are decoupled. The model is applied to quantify the structure of the smectic phase of isotactic polypropylene (i-PP)." @default.
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• W2134662180 date "2001-06-01" @default.
• W2134662180 modified "2023-09-23" @default.
• W2134662180 title "A direct correlation function for mesomorphic polymers and its application to the ‘smectic’ phase of isotactic polpropylene" @default.
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• W2134662180 doi "https://doi.org/10.1016/s0032-3861(00)00914-9" @default.
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